Thursday January 10th, 2019

Proposition of Contractual / Research stay : Study of molecules/oxide substrates by mixing calorimetry

POSITION FILLED

 

Research Project:

Study of molecules/oxide substrates by mixing calorimetry

 

 

Research Team: CIRIMAT

Project duration: 4-6 months, starting between january and march 2019

Supervisors: Christophe Drouet, Maëlenn Aufray

Project

Several industrial processes involve interactions between molecular species dissolved in a solvent and a substrate surface. By modifying the chemical nature of the molecule and/or the substrate, it then becomes possible to modulate  the type and energy of interaction involved. The latter is however rarely evaluated on a quantitative basis, and the selection of molecule/substrate systems often relies on observations/characterization performed afterward rather than in situ. In this project, in direct link with a French industrial partner, the interaction between a selection of molecules and substrates of applicative interest will be measured by mixing microcalorimetry. The enthalpies measured will allow comparing the systems tested. The effect of various parameters (solvent, molar concentration, substrate mass, pH…) will be followed. Physicochemical characterization will also be performed on selected substrates before and after interaction as well as on supernatants, and kinetics/isotherms of adsorption will be determined, if necessary, on the most relevant systems.

Financing on industrial research contract. Start within the 3 next months.

 

Profile & Skills

From 2-year undergraduate technical diploma to Master’s degree, background in materials science and/or physicchemistry. Knowledge in chemical thermodynamics would be a plus.

 

How to apply?

Please send your CV and cover letter to

Toulouse

Structure d’accueil : CIRIMAT

Start: between january and march 2019

Duration: 12 months (renewable once)